Recent Developments in Palladium-Catalysed Non-Directed C–H Bond Activation in Arenes

Autor:	Kåre B. Jørgensen, M. Ángeles Fernández-Ibáñez, Sindhu Kancherla
Přispěvatelé:	Synthetic Organic Chemistry (HIMS, FNWI)
Rok vydání:	2019
Předmět:	C h bond 010405 organic chemistry Chemistry Site selectivity Organic Chemistry chemistry.chemical_element Bond formation Alkylation 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences Carbonylation Palladium
Zdroj:	Synthesis, 51(3), 643-663. Georg Thieme Verlag
ISSN:	1437-210X 0039-7881
Popis:	Over the past decades, organic chemists have focussed on developing new approaches to directed C–H functionalisations, where the site selectivity is steered by the presence of a directing group (DG). Nonetheless, in recent years, more and more non-directed strategies are being developed to circumvent the requisite directing group, making C–H functionalisations more generic. This short review focuses on the latest developments in palladium-catalysed non-directed C–H functionalisations of aromatic compounds.1 Introduction2 C–C Bond Formation2.1 C–H Arylation2.2 C–H Alkylation2.3 C–H Alkenylation2.4 C–H Carbonylation3 C–Heteroatom Bond Formation3.1 C–O Bond Formation3.2 C–N Bond Formation3.3 C–S Bond Formation4 Conclusion
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd02352215b486bdbb1363492f4f4189 https://doi.org/10.1055/s-0037-1610852 Zobrazit plný text záznamu