Optical T-T absorption of salicylidene-p-toluidine in solution
Autor: | İpek Ş. Karaaslan, Fuat Bayrakçeken |
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Rok vydání: | 2006 |
Předmět: |
Diffraction
Optics and Photonics Absorption spectroscopy Toluidines Chemistry Analytical chemistry Temperature Physics::Optics Activation energy Photochemistry Atomic and Molecular Physics and Optics Analytical Chemistry Optical pumping Solutions Microsecond Flash (photography) Cyclohexanes Flash photolysis Absorption (electromagnetic radiation) Instrumentation Spectroscopy |
Zdroj: | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 68(5) |
ISSN: | 1386-1425 |
Popis: | The observation of triplet-triplet absorption of salicylidene-p-toluidine, is complicated by the possible colored isomer formation during the optical pumping. The short-lived (singlet-singlet) and long-lived (triplet-triplet) absorption spectra were recorded phographically by microsecond flash and nanosecond laser flash photolysis techniques. Salicylidene-aniline complexes were purified by repeated recrystallisation until further recrystallisation produced no further changes for X-ray diffraction pattern and optical absorption, emission properties. |
Databáze: | OpenAIRE |
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