Are deep eutectic solvents a real alternative to ionic liquids in metal-catalysed reactions?
| Autor: | Sara Gracia-Barberán, Alejandro Leal-Duaso, Elísabet Pires |
|---|---|
| Přispěvatelé: | Ministerio de Ciencia, Innovación y Universidades (España), Agencia Estatal de Investigación (España), Gobierno de Aragón, European Commission, Ministerio de Economía y Competitividad (España) |
| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname |
| ISSN: | 2018-0934 |
| Popis: | This microreview tries to answer the question: Are Deep Eutectic Solvents a real alternative to Ionic Liquids in metal-catalysed reactions? We have gathered the outstanding results of the use of DES in metal-catalysed processes and we have compared them to the ones with ILs. The huge possibilities of combinations of the components of the DES provide a vast number of different solvents with tunable properties. These DES have been successfully applied to different reactions such as, couplings or hydrogenations, among others. But additional work is still be necessary to explore the use of DES in other reactions and to go in depth in the study of the influence of the nature of the DES. Finally, we also present the rise in a new family of solvents, bio-based ionic liquids, complementary to the use of DES in order to fully substitute traditional ILs. This work has been supported by the Ministerio de Ciencia, Innovación y Universidades (Project RTI2018-093431-B-I00), the Gobierno de Aragón (group E37_20R) and the European Regional Development Funds. |
| Databáze: | OpenAIRE |
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