Autor:	Glen B. Deacon, Graeme John Moxey, Peter C. Junk
Rok vydání:	2010
Předmět:	Inorganic Chemistry Metal Alkaline earth metal Chemistry visual_art Inorganic chemistry visual_art.visual_art_medium Fluorite
Zdroj:	Dalton Transactions. 39:5620
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c0dt00122h
Popis:	Treatment of Ca or Sr metal with Hg(C(6)F(5))(2) and 2,4,6-trimethylphenol (HOmes) in 1,2-dimethoxyethane (dme) at room temperature resulted in C-F bond activation, giving rise to the unique fluoro(aryloxo)alkaline earth cages [Ca(5)(mu(4)-F)(mu(3)-F)(4)(mu-Omes)(4)(Omes)(dme)(4)] 1 and [Sr(10)(mu(4)-F)(4)(mu(3)-F)(4)(mu-Omes)(12)(dme)(4)] 2, which can be viewed as arrested fluorite structures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bcccfed2e54264825d5d1f8ecbd1bad6 https://doi.org/10.1039/c0dt00122h Zobrazit plný text záznamu