A boron, nitrogen-containing heterocyclic carbene (BNC) as a redox active ligand: synthesis and characterization of a lithium BNC-aurate complex

Autor:	Yoshitaka Kimura, Leonardo I. Lugo-Fuentes, Souta Saito, J. Oscar C. Jimenez-Halla, Joaquín Barroso-Flores, Yohsuke Yamamoto, Masaaki Nakamoto, Rong Shang
Rok vydání:	2022
Předmět:	Inorganic Chemistry
Zdroj:	Dalton Transactions. 51:7899-7906
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d2dt01083f
Popis:	Stabilization of low oxidation gold anions as aurate or auride by organic ligands has long been a synthetic challenge, owing to the proneness of low-valent gold centres to cluster. Despite being the most electronegative metal, isolable gold(I) aurate complexes have only been obtained from a few σ-withdrawing organo- and organo-main group ligands. Stabilization of highly-reduced gold complexes by π-modulating redox active ligands has only been achieved by cyclic (amino)(alkyl)carbene (CAAC), which is limited to 1e
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bc9b46262d29870cbdbea4d02489530e https://doi.org/10.1039/d2dt01083f Zobrazit plný text záznamu