A novel chiral inorganic mesoporous silica used as a stationary phase in GC

Autor:	Li-Ming Yuan, Xue-Xian Chen, Yu‐Yu He, Lan Luo, Qing Pu, Sheng-Ming Xie, Yan‐Xia Li, Jun-Hui Zhang
Rok vydání:	2019
Předmět:	Pharmacology chemistry.chemical_classification 010405 organic chemistry Organic Chemistry Alcohol Mesoporous silica engineering.material 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Analytical Chemistry Amino acid chemistry.chemical_compound chemistry Coating Capillary column Stationary phase Drug Discovery engineering Organic chemistry Thermal stability Gas chromatography Spectroscopy
Zdroj:	ChiralityREFERENCES. 31(12)
ISSN:	1520-636X
Popis:	Chiral mesoporous silica (CMS) has attracted widespread attention because of some unique properties, such as high surface area, uniformly structured nanoscale cavities, and excellent chemical and thermal stability. In this work, we report the utilization of a CMS as the stationary phase for the separation of racemates in gas chromatography (GC). A CMS-coated capillary column was fabricated by a dynamic coating method. Eighteen racemates belonging to different classes of organic compounds were separated on this column, including chiral alcohols, aldehydes, ketones, organic acids, halohydrocarbons, alkenes, alcohol amines, epoxides, and amino acid derivatives. In addition, linear alkanes, alcohols, and aromatic hydrocarbons have also been resolved.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bc7d1c68350b7f7b4cfd04c23db3f732 https://pubmed.ncbi.nlm.nih.gov/31633239 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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