{2-[(S)-({2-[(S)-1-Benzylpyrrolidine-2-carboxamido]phenyl}(phenyl)methylene)amino]-4-hydroxybutanoato-κ4N,N′,N′′,O}nickel(II)
| Autor: | Alexander Popkov, Milan Nádvorník, Jozef Kožíšek |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
chemistry.chemical_element
Medicinal chemistry NI(II) COMPLEXES C-13 NMR-SPECTRA chemistry.chemical_compound 1-benzylpyrrolidine Atom Side chain AMINO-ACIDS General Materials Science Methylene ASYMMETRIC-SYNTHESIS NICKEL(II) COMPLEX GeneralLiterature_REFERENCE(e.g. dictionaries encyclopedias glossaries) Metal-Organic Papers Schiff base Chemistry Hydrogen bond Enantioselective synthesis GLYCINE General Chemistry Condensed Matter Physics SCHIFF-BASE Nickel (S)-2-(N-BENZYLPROLYL)AMINOBENZOPHENONE ComputingMethodologies_DOCUMENTANDTEXTPROCESSING |
| Zdroj: | Acta Crystallographica Section E-Structure Reports Online, 64, M364-U826. BLACKWELL PUBLISHING Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| DOI: | 10.1107/s1600536808000949 |
| Popis: | The central Ni atom of the title compound, [Ni(C(29)H(29)N(3)O(4))], is coordinated by three N atoms [Ni-N = 1.955 (2), 1.844 (2) and 1.872 (2) Å] and by one O atom [Ni-O = 1.862 (2) Å] in a pseudo-square-planar geometry. The conformation of the hydroxy-butanoate side chain is controlled by a strong intra-molecular hydrogen bond (H⋯O = 1.84 Å). |
| Databáze: | OpenAIRE |
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