Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination

Autor:	Yaju Chen, Liping Huang, Xiantai Zhou, Liwei Zhang, Xin Xu, Jehan Kim, Hongbing Ji, Junhui Bao, Zhegang Huang, Shanshan Wu
Rok vydání:	2020
Předmět:	Inorganic Chemistry Metal Materials science Chemical engineering visual_art Kinetics visual_art.visual_art_medium Metal-organic framework Titration Bending Ton Curvature Catalysis
Zdroj:	Dalton Transactions. 49:2403-2406
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c9dt04668b
Popis:	A tubular MOF with adequate active sites is prepared by the bending of metal-coordinated honeycombed frameworks via titration and shows fast catalytic kinetics with lower catalytic loading for CO2 conversion. The TON is observed to be 2300 and the corresponding TOF of up to 173 h-1 is achieved for the first time.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bc329903bca0241eeebd6a7787ba1c61 https://doi.org/10.1039/c9dt04668b Zobrazit plný text záznamu