Reactions at solid-liquid interfaces: contrasting chemistry at different crystal faces in the hydroxide-induced reactive dissolution of p-chloranil as revealed by channel flow cell voltammetry

Autor: Richard G. Compton, Emma Hill, John H. Atherton, Richard R. Lloyd-Williams
Jazyk: angličtina
Rok vydání: 2016
Předmět:
DOI: 10.1007/s100080050162
Popis: The (100), (010) and (001) faces of monoclinic crystals of the organic solid p-chloranil display contrasting reactivities towards hydrolytic dissolution induced by aqueous hydroxide ions. The differing behaviour is rationalised in terms of the functional groups exposed in the different faces.
Databáze: OpenAIRE