Bis(pentafluorophenyl)phenothiazylborane – an intramolecular frustrated Lewis pair catalyst for stannane dehydrocoupling

Autor:	Jordan N. Bentley, Ekadashi Pradhan, Tao Zeng, Christopher B. Caputo
Rok vydání:	2020
Předmět:	010405 organic chemistry Chemistry Substituent 010402 general chemistry 01 natural sciences Heterolysis Stannane Medicinal chemistry Frustrated Lewis pair 0104 chemical sciences Homolysis Catalysis Inorganic Chemistry chemistry.chemical_compound Intramolecular force Reactivity (chemistry)
Zdroj:	Dalton Transactions. 49:16054-16058
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d0dt00506a
Popis:	We synthesized a novel Lewis acidic aminoborane containing a phenothiazyl substituent and demonstrated its potential to catalytically promote the dehydrocoupling of tin hydrides. The observed reactivity would imply a homolytic frustrated Lewis pair type mechanism, however computational analysis suggests a heterolytic mechanism for this reaction. This result represents one of the first frustrated Lewis pair systems to dehydrocouple stannanes in a heterolytic fashion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bbd66d2f6bcf01247fde583ff6a21fa4 https://doi.org/10.1039/d0dt00506a Zobrazit plný text záznamu