Change of the magnetic coupling of a metal-organic complex with the substrate by a stepwise ligand reaction
| Autor: | Gelavizh Ahmadi, Lukas Braun, Jose Ignacio Pascual, Katharina J. Franke, Benjamin W. Heinrich, Valentin L. Müller |
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| Rok vydání: | 2013 |
| Předmět: |
Models
Molecular Porphyrins Ligand Chemistry Mechanical Engineering Iron Magnetic Phenomena Substrate (chemistry) Bioengineering General Chemistry Condensed Matter Physics Resonance (chemistry) Photochemistry Ligands Inductive coupling law.invention law Coordination Complexes Microscopy Scanning Tunneling Intramolecular force Molecule General Materials Science Kondo effect Gold Scanning tunneling microscope |
| Zdroj: | Nano letters. 13(10) |
| ISSN: | 1530-6992 |
| Popis: | The surface-assisted intramolecular ligand reaction of a porphyrin molecule adsorbed on Au(111) is studied by scanning tunneling microscopy and spectroscopy. The temperature-induced stepwise transformation of iron octaethylporphyrin proceeds via a concentric electrocyclic ring closure, with the final product iron tetrabenzoporphyrin being identified by its characteristic Kondo resonance. Along with the transformation of the organic ligand, changes in the magnetic fingerprint are observed, indicating an increasing coupling of the iron spin with the substrate electrons. |
| Databáze: | OpenAIRE |
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