Transamidation of aromatic amines with formamides using cyclic dihydrogen tetrametaphosphate

Autor:	Kishor Kumar Chouhan, Deep Chowdhury, Arup Mukherjee
Rok vydání:	2022
Předmět:	Kinetics Biological Products Formamides Organic Chemistry Amines Physical and Theoretical Chemistry Amides Biochemistry Catalysis Hydrogen
Zdroj:	Organic & Biomolecular Chemistry. 20:7929-7935
ISSN:	1477-0539 1477-0520
DOI:	10.1039/d2ob00882c
Popis:	Amide fragments are found to be one of the key constituents in a wide range of natural products and pharmacologically active compounds. Herein, we report a simple and efficient procedure for transamidation with a cyclic dihydrogen tetrametaphosphate. The protocol is simple, does not require any additives, and encompasses a broad substrate scope. To comprehend the mechanism of the present methodology, detailed spectroscopic and kinetic studies were undertaken.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bb8caa314c9c3a0c784ea3ab576e3239 https://doi.org/10.1039/d2ob00882c Zobrazit plný text záznamu