Molecular structure and EPR spectra studies of saccharinate complexes with 4-acetylpyridine
| Autor: | Bünyamin Karabulut, Esat Bozkurt, Yunus Çelik, İbrahim Uçar |
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| Přispěvatelé: | Ondokuz Mayıs Üniversitesi |
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
Chemistry
Doping Inorganic compounds General Chemistry Crystal structure Condensed Matter Physics Spectral line law.invention Ion X-ray diffraction Crystallography law Electron paramagnetic resonance (EPR) Magnetic properties Molecule General Materials Science Electron paramagnetic resonance Ground state Hyperfine structure Infrared spectroscopy |
| Popis: | Celik, Yunus/0000-0003-0515-6744 WOS: 000304632100007 The crystal structures of [co(4-acpy)(2)(H2O)(4)] (sac)(2) (1) and [Zn(4-acpy)(2)(H2O)(4)] (sac)(2) (2) (4-acpy: 4-acetylpyridine, sac: saccharinate) complexes have been investigated by X-ray diffraction techniques. The magnetic environments of Cu2+ doped [Co(4-acpy)(2)(H2O)(4)] (sac)(2) and [Zn(4-acpy)(2)(H2O)(4)] (sac)(2) complexes have been identified by electron paramagnetic resonance (EPR) technique. Principal values of g and hyperfine tensors are determined and the ground state wave functions of Cu2+ ions are obtained using EPR parameters. The vibrational spectra were also discussed in relation with the other compounds containing saccharinate and 4-acetylpyridine complexes. (C) 2012 Elsevier Ltd. All rights reserved. |
| Databáze: | OpenAIRE |
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