| Autor: |
Kai Zou, Qihua Li, Jingquan Fan, Hebing Tang, Lixin Chen, Shuxia Tao, Tingting Xu, Wei Huang |
| Přispěvatelé: |
Materials Simulation & Modelling, Group Smeulders, Energy Technology, Computational Materials Physics, EIRES Chem. for Sustainable Energy Systems, Center for Computational Energy Research |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
|
| Zdroj: |
ACS Materials Letters, 4(6), 1101-1111. American Chemical Society |
| ISSN: |
2639-4979 |
| Popis: |
Surface passivation has been demonstrated to be an effective strategy to reduce defects of hybrid halide perovskite films for making efficient and stable perovskite solar cells (PSCs). Especially the strong interaction between the passivation agents and the perovskite films is favorable for achieving a durable passivation effect. Pyridine derivatives with bidentate anchoring groups can interact with the uncoordinated Pb2+and minimize perovskite defects. Herein, in order to rationally design bidentate passivation agents, the passivation effects of pyridine (Py) and its derivatives (Py-X) with different functional groups of amino, carboxyl acid, and aldehyde are compared in carbon-based perovskite solar cells (C-PSCs) for the first time. Py-NH2is found to passivate the perovskite CH3NH3PbI3film the best among all the passivation agents. The N atoms on both the pyridine ring and the amino group with lone pair electrons can combine with the uncoordinated Pb2+, effectively reducing the defect density in the Py-NH2-treated perovskite film. First-principles density functional theory (DFT) calculations reveal that the strong interaction between Py-NH2and CH3NH3PbI3strengthens Pb-I bond and hinders the formation of I vacancies. Carbon-based perovskite solar cells (C-PSCs) passivated by Py-NH2achieve a champion power conversion efficiency (PCE) of 14.75%, compared to 11.55% of the control device. The Py-NH2passivated C-PSCs also exhibit good long-term stability, retaining more than 90% of the initial efficiency after 30 days of storage in air with 35-45% relative humidity. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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