Influence of moisture content on NO2 sorption ability of cedar wood
Autor: | Kozo Kanayama, Kenji Umemura, Miyuki Nakagawa, Shuichi Kawai |
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Rok vydání: | 2021 |
Předmět: |
inorganic chemicals
Moisture content Building construction Chemistry Forestry Japanese cedar wood Sorption respiratory system SD1-669.5 complex mixtures respiratory tract diseases Biomaterials chemistry.chemical_compound Cedar wood Adsorption Volume (thermodynamics) Nitric acid Environmental chemistry Aeration Water content TH1-9745 Nitrogen dioxide (NO2) sorption Nitrogen dioxide (NO₂) sorption |
Zdroj: | Journal of Wood Science, Vol 67, Iss 1, Pp 1-10 (2021) |
ISSN: | 1611-4663 1435-0211 |
DOI: | 10.1186/s10086-021-01961-z |
Popis: | This study examined the influence of moisture content (MC) on NO2 sorption ability of cedar (Cryptomeria japonica) wood using the specimens with different MCs. Four MC conditions were applied, namely 0%, 8.6%, 12.7% and 16.5%, based on the differences of bonding condition of water molecule in the wood substances. As a result, the NO2 sorption volume increased drastically due to the presence of water, and as the MC increased, the NO2 sorption volume increased slightly. The NO generation volume and nitric acid concentration in the specimens were evaluated after an aeration test, and it was strongly indicated that the NO2 reacted with water in the specimen, and that the NO generation volume increased as the content of multilayer adsorbed water increased. The nitric acid seemed to be formed by the reaction between NO2 and water, and it was then held in the specimen. Based on the NO2 sorption volume calculated using the NO generation volume, it was shown that the NO2 sorption after 12-h aeration was caused mainly by the reaction between NO2 and water. Furthermore, the presence of both water and extractives contributed to the NO2 sorption in the initial period, and the presence of water contributed greatly to the NO2 sorption over the long term. |
Databáze: | OpenAIRE |
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