Tandem ring-opening/closing reactions of N-Ts aziridines and aryl propargyl alcohols promoted by t-BuOK
Autor: | Wen-Jing Xiao, Qi-Bin Liu, Xin Li, Xiu-Wen Han, Duo-Sheng Wang, Liang Wang, Yong-Gui Zhou |
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Rok vydání: | 2009 |
Předmět: |
Reaction mechanism
Molecular Structure Propanols Aryl Organic Chemistry Asymmetric hydrogenation Aziridines Ring (chemistry) Biochemistry Medicinal chemistry Catalysis chemistry.chemical_compound chemistry Cyclization Reagent Alkynes Propargyl Oxazines Michael reaction Organic chemistry Combinatorial Chemistry Techniques Indicators and Reagents Physical and Theoretical Chemistry |
Zdroj: | Organic letters. 11(5) |
ISSN: | 1523-7052 |
Popis: | t-BuOK was found to be an effective promoting reagent for tandem ring-opening/closing reactions of various N-Ts aziridines and aryl propargyl alcohols to afford dihydroxazine derivatives in moderate to good yields. A plausible reaction mechanism has been proposed. |
Databáze: | OpenAIRE |
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