Folding of phosphodiester-linked donor-acceptor oligomers into supramolecular nanotubes in water
| Autor: | Gérard Vergoten, Michael Smietana, Jean-Jacques Vasseur, Kévan Pérez de Carvasal, Nesrine Aissaoui, François Morvan, Gaëtan Bellot |
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| Přispěvatelé: | Institut des Biomolécules Max Mousseron [Pôle Chimie Balard] (IBMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Centre de Biochimie Structurale [Montpellier] (CBS), Institut National de la Santé et de la Recherche Médicale (INSERM)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Institute for Translational Research in Inflammation - U 1286 (INFINITE (Ex-Liric)), Institut National de la Santé et de la Recherche Médicale (INSERM)-Université de Lille-Centre Hospitalier Régional Universitaire [Lille] (CHRU Lille) |
| Rok vydání: | 2021 |
| Předmět: |
Phosphoramidite
010405 organic chemistry Stereochemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Metals and Alloys Supramolecular chemistry General Chemistry [CHIM.THER]Chemical Sciences/Medicinal Chemistry Random hexamer 010402 general chemistry 01 natural sciences Acceptor Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Folding (chemistry) chemistry.chemical_compound chemistry Diimide Phosphodiester bond Materials Chemistry Ceramics and Composites Solvophobic |
| Zdroj: | Chemical Communications Chemical Communications, 2021, 57 (34), pp.4130-4133. ⟨10.1039/D1CC01064F⟩ |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | International audience; Inspired by the automated synthesis of DNA on solid support, electron-rich dialkxoynaphthalene dialkoxynaphthalene (DAN) donor and electron-deficient-naphthalene-tetracarboxylic diimide (NDI) acceptor, amphiphilic foldamers have been synthesised from their respective phosphoramidite building blocks. The folding of the phosphodiester-linked hexamer (DAN-NDI)3 revealed in water the formation in water of regular supramolecular nanotubes resulting from the self-assembly of multiple hexamers stabilized by donor/acceptor interactions and solvophobic effect. |
| Databáze: | OpenAIRE |
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