Isotope shifts and hyperfine-structure-splitting constants of the 4d-5p transition of Kr II at lambda =729 nm

Autor: Hans A. Schuessler, Evans Rm, Fischer Cf, Li Yf, Buchinger F, A Alousi, Idrees M
Rok vydání: 1992
Předmět:
Zdroj: Physical review. A, Atomic, molecular, and optical physics. 45(9)
ISSN: 1050-2947
Popis: Collinear fast-beam laser spectroscopy has been used to measure the hyperfine splittings and the isotope shifts in the 4{ital p}{sup 4}4{ital d} {sup 4}{ital D}{sub 7/2}--4{ital p}{sup 4}5{ital p} {sup 4}{ital P}{degree}{sub 5/2} ({lambda}=729 nm) transition of singly ionized Kr. The measured isotope shifts are very large due to a large specific-mass effect that is caused by the strong momentum correlations of the 4{ital d} electron with the core electrons. Hartree-Fock and multiconfiguration Hartree-Fock (MCHF) calculations of the specific-mass shift were carried out and are compared to the measurements. The MCHF calculation yields excellent agreement with the experimental results.
Databáze: OpenAIRE