Thermal decomposition of CuProp2: In-situ analysis of film and powder pyrolysis
| Autor: | Teresa Puig, Jordi Farjas, Silvia Rasi, Pere Roura-Grabulosa, Fabrizio Silveri, Susagna Ricart, Xavier Obradors |
|---|---|
| Přispěvatelé: | Ministerio de Ciencia, Innovación y Universidades (España), Generalitat de Catalunya, Universidad de Girona |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Thermogravimetric analysis
Materials science Evolved gas analysis 020209 energy chemistry.chemical_element Anàlisi tèrmica Copper propionate 02 engineering and technology Analytical Chemistry 020401 chemical engineering CSD methods 0202 electrical engineering electronic engineering information engineering Thermochemistry Thermal analysis 0204 chemical engineering Thermal decomposition Copper Decomposition Fuel Technology Chemical engineering chemistry Metal carboxylates Pyrolysis Piròlisi |
| Zdroj: | Rasi, Silvia Fabrizio, Silveri Ricart, Susagna Obradors, Xavier Puig, Teresa Roura Grabulosa, Pere Farjas Silva, Jordi 2019 Thermal decomposition of CuProp2: In-situ analysis of film and powder pyrolysis Journal of Analytical and Applied Pyrolysis 140 312 320 © Journal of Analytical and Applied Pyrolysis, 2019, vol. 140, p. 312-320 Articles publicats (D-F) DUGiDocs – Universitat de Girona instname Digital.CSIC. Repositorio Institucional del CSIC |
| ISSN: | 0165-2370 |
| Popis: | The thermal decomposition of CuProp in the form of film and powder was studied in different atmospheres by means of thermal analysis techniques (TG-MS, TG-IR, EGA), chemical-structural methods (FTIR, XRD, EA) and computational thermochemistry (VASP/PBE). The decomposition mechanism in terms of volatiles evolved was disclosed with the aid of ab-initio modeling; it was found to be dependent on the gas diffusion in and out of the sample and accelerated by a humid atmosphere. In films, the copper redox behavior showed sensitivity to the residual atmosphere. Finally, the role of the metal center is discussed in the frame of a general decomposition mechanism for metal propionates. This work was supported by Ministerio de Ciencia, Innovación y Universidades (grant numbers RTI2018-095853-B-C21 and RTI2018-095853-B-C22), by the Center of Excellence Severo Ochoa (SEV-2015-0496), the Generalitat of Catalunya (SGR753 and SGR948) and by the Universitat de Girona (UdG, contract number MPCUdG2016/059). SR and FS thanks the Universitat de Girona (UdG) and the Cardiff University School of Chemistry, respectively, for their fully-funded PhD scholarships. The authors also wish to thank the Scientific services of the UdG and of the Institute of Materials Science of Barcelona (ICMAB). Computing facilities were provided by ARCCA at Cardiff University, HPC Wales, and via the membership of the UK’s Materials Chemistry Consortium (MCC), which is funded by EPSRC (EP/F067496). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect