A Baker–Venkataraman retro-Claisen cascade delivers a novel alkyl migration process for the synthesis of amides
Autor: | Timothy J. Snape, Dana Ameen |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 56:1816-1819 |
ISSN: | 0040-4039 |
Popis: | A simple extension of the carbamoyl Baker–Venkataraman rearrangement has been developed. If residual water in the reaction is not strictly excluded a Baker–Venkataraman retro-Claisen cascade takes place, giving amide products, in which an alkyl group apparently migrates between two functionalities of the substrate. |
Databáze: | OpenAIRE |
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