Spectroscopic investigation of the covalence of An( iii ) complexes with tetraethylcarboxamidopyridine
| Autor: | Thomas Sittel, Patrik Weßling, Dennis Großmann, Eliane Engels, Andreas Geist, Petra J. Panak |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Dalton Transactions, 51 (20), 8028–8035 |
| ISSN: | 1477-9226 1477-9234 |
| Popis: | M(iii)–O and M(iii)–N interaction in [M(Et-Pic)3]3+ (M = Ln and Am; Et-Pic: N,N,N′,N′-tetraethyl-2,6-carboxamidopyridine) complexes were studied. NMR and TRLFS data suggest an increased partial covalent interaction in the An(iii)–N bond. |
| Databáze: | OpenAIRE |
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