Biphase hydroformylation catalyzed by rhodium in combination with a water-soluble pyridyl-triazole ligand
| Autor: | Emanuele Amadio, Md. Mahbubul Alam, Stefano Paganelli, Matteo Bertoldini, Valentina Beghetto, Alberto Scrivanti, Patrizia Canton |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Materials Chemistry2506 Metals and Alloys
chemistry.chemical_element 010402 general chemistry 01 natural sciences Settore CHIM/04 - Chimica Industriale Catalysis Rhodium Styrene Inorganic Chemistry chemistry.chemical_compound Polymer chemistry Materials Chemistry Organic chemistry Aqueous biphasic catalysis Chemoselectivity Physical and Theoretical Chemistry Settore CHIM/02 - Chimica Fisica Aqueous solution 010405 organic chemistry Ligand Aqueous two-phase system 0104 chemical sciences Sulphonated nitrogen ligand chemistry Hydroformylation Nanoparticles |
| Popis: | [RhCl(COD)] 2 in combination with a water soluble sulphonated pyridyl-triazolyl N,N -bidentate ligand efficiently catalyzes styrene and 1-hexene hydroformylation in water/organic solvent biphasic systems. The catalyst displays a good activity affording mixtures of linear and branched aldehydes with complete chemoselectivity. The aqueous catalytic phase may be recycled four times giving complete substrate conversion by 18 h. Mercury-poisoning experiments and transmission electron microscopy indicate that, after the first catalytic run, rhodium is present in the aqueous phase in nanoparticle form. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|