A Double-Decker Silver(I) Coordination Polymer of 1-Methylpyrene with Columnar Aromatic Stacks. Effect of Substituting Groups on Structure of Silver(I) Complexes with Polycyclic Aromatic Hydrocarbons

Autor:	Megumu Munakata, Yusaku Suenaga, Masae Kasahara, Jian Chu Zhong, Takayoshi Kuroda-Sowa, Hisashi Konaka, Masahiko Maekawa
Rok vydání:	2001
Předmět:	Inorganic Chemistry chemistry.chemical_classification Perchlorate chemistry.chemical_compound chemistry Coordination polymer Inorganic chemistry Polymer chemistry Stacking 1-methylpyrene Polymer Physical and Theoretical Chemistry Double decker
Zdroj:	Inorganic Chemistry. 40:7087-7090
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic010668u
Popis:	A novel silver(I) coordination polymer of 1-methylpyrene (mpyr) with double-decker motifs, {[Ag2(mpyr)2(ClO4)2]0.5benzene}n (1), was synthesized and characterized. Polymer 1 consists of 1-D double-decker chains, which are formed by dimeric double-decker units ([Ag(mpyr)(ClO4)]2) through the linkage of the perchlorate groups. In addition, the dimeric moieties between the adjacent chains are stacked to lead to column π−π stacks. Therefore, complex 1 can also be regarded as a 2-D stacking polymer. The effects of substituting groups, and other factors, on the structure of silver(I) complexes with polycyclic aromatic hydrocarbons are also discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b9afb02258d7c25e8e6054d04ebee179 https://doi.org/10.1021/ic010668u Zobrazit plný text záznamu