An investigation of palladium-catalyzed Stille-type cross-coupling of nitroarenes in perylenediimide series

Autor:	Aline Makhloutah, Danylo Hatych, Thomas Chartier, Lou Rocard, Antoine Goujon, François-Xavier Felpin, Piétrick Hudhomme
Rok vydání:	2022
Předmět:	Organic Chemistry Physical and Theoretical Chemistry Biochemistry
Zdroj:	Organic & Biomolecular Chemistry. 20:362-365
ISSN:	1477-0539 1477-0520
Popis:	We report herein an unprecedented palladium-catalyzed cross-coupling reaction between mononitro-perylenediimide (PDI) and various arylstannanes. Optimized conditions developed with this Stille-type reaction allow the grafting of (hetero)aryls of various electronic nature in the bay region of PDIs. Moreover, we capitalized on the high selectivity of this cross-coupling through the desymmetrization of the dinitro-PDI substrate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b989a80216eb19e5f14139aaf5747bcc https://doi.org/10.1039/d1ob02291a Zobrazit plný text záznamu