Oxidative ring expansion of a low-coordinate palladacycle : synthesis of a robust T-shaped alkylpalladium(II) complex
| Autor: | Adrian B. Chaplin, Matthew J. G. Sinclair |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
TP
010405 organic chemistry Chemistry Ligand chemistry.chemical_element Oxidative phosphorylation 010402 general chemistry Ring (chemistry) 01 natural sciences 0104 chemical sciences Pincer movement Inorganic Chemistry Transition metal Polymer chemistry Materials Chemistry QD Physical and Theoretical Chemistry Palladium |
| ISSN: | 0020-1693 |
| Popis: | The synthesis of an unusual T-shaped alkylpalladium(II) complex featuring a cyclometalated tri-tert-butylphosphineoxide ligand by oxidation of the corresponding cyclometalated tri-tert-butylphosphine complex with PhIO is reported. We speculate that this reaction proceeds by formation of a transient palladium oxo intermediate and there are structural similarities with a late transition metal exemplar: Milstein’s seminal pincer ligated Pt(IV) oxo (Nature 2008, 455, 1093–1096). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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