C–H amidation of 2-aryl azlactones under iridium(iii) catalysis: access to chiral amino acids

Autor:	Min Seo Park, Eunjae Chung, Neeraj Kumar Mishra, Sang Hoon Han, Sangil Han, Saegun Kim, In Su Kim
Rok vydání:	2022
Předmět:	Azides Molecular Structure Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Amino Acids Iridium Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:13365-13368
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d2cc05245h
Popis:	First application of azlactone as a directing group in Ir(iii)-catalyzed C–H amidation is described herein. A noteworthy aspect of this method is the synthesis of chiral N-amidobenzoyl amino acids with high enantiomeric excess via organocatalysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b979c34d67dbab9f5d12c8b603920717 https://doi.org/10.1039/d2cc05245h Zobrazit plný text záznamu