Achieving Nickel Catalyzed C-S Cross-Coupling under Mild Conditions Using Metal-Ligand Cooperativity

Autor:	Nanda D. Paul, Rina Sikari, Suman Sinha, Rakesh Mondal, Anannya Saha, Siuli Das, Gargi Chakraborty
Rok vydání:	2019
Předmět:	010405 organic chemistry Ligand Aryl Organic Chemistry chemistry.chemical_element Cooperativity 010402 general chemistry 01 natural sciences Redox Oxidative addition Reductive elimination 0104 chemical sciences Nickel chemistry.chemical_compound Catalytic cycle chemistry Polymer chemistry
Zdroj:	The Journal of organic chemistry. 84(7)
ISSN:	1520-6904
Popis:	A simple and efficient approach of C-S cross-coupling of a wide variety of (hetero)aryl thiols and (hetero)aryl halides under mild conditions, mostly at room temperature, catalyzed by well-defined singlet diradical Ni(II) catalysts bearing redox noninnocent ligands is reported. Taking advantage of ligand centered redox events, the high-energetic Ni(0)/Ni(II) or Ni(I)/Ni(III) redox steps were avoided in the catalytic cycle. The cooperative participation of both nickel and the coordinated ligands during oxidative addition/reductive elimination steps allowed us to perform the catalytic reactions under mild conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b9641cd14b5ae386a9cfb254c6ce1a08 https://pubmed.ncbi.nlm.nih.gov/30855958 Zobrazit plný text záznamu