In situ environmental HRTEM discloses low temperature carbon soot oxidation by ceria-zirconia at the nanoscale

Autor: Philippe Vernoux, Eleonora Aneggi, Mimoun Aouine, Alessandro Trovarelli, Jordi Llorca
Přispěvatelé: Universitat Politècnica de Catalunya. Departament d'Enginyeria Química, Universitat Politècnica de Catalunya. NEMEN - Nanoenginyeria de materials aplicats a l'energia, IRCELYON-Microscopie (MICROSCOPIE), Institut de recherches sur la catalyse et l'environnement de Lyon (IRCELYON), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), IRCELYON-Catalytic and Atmospheric Reactivity for the Environment (CARE)
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Materials Chemistry2506 Metals and Alloys
In situ
Oxygen transfer
Materials science
Materials nanoestructurals
Catalitzadors
chemistry.chemical_element
010402 general chemistry
medicine.disease_cause
Enginyeria dels materials [Àrees temàtiques de la UPC]
Oxidació
7. Clean energy
01 natural sciences
Redox
Catalysis
Coatings and Films
Enginyeria química [Àrees temàtiques de la UPC]
Oxidation
Electronic
Materials Chemistry
medicine
Cubic zirconia
Optical and Magnetic Materials
High-resolution transmission electron microscopy
Nanoscopic scale
Carboni
Catalysts
010405 organic chemistry
Chemistry (all)
Metals and Alloys
General Chemistry
[CHIM.CATA]Chemical Sciences/Catalysis
Nanostructured materials
[SDE.ES]Environmental Sciences/Environmental and Society
Soot
Carbon
0104 chemical sciences
Surfaces
Coatings and Films

Electronic
Optical and Magnetic Materials

Surfaces
Chemical engineering
chemistry
Ceramics and Composites
2506
Zdroj: Chemical Communications
Chemical Communications, Royal Society of Chemistry, 2019, 55 (27), pp.3876-3878. ⟨10.1039/c8cc09011d⟩
UPCommons. Portal del coneixement obert de la UPC
Universitat Politècnica de Catalunya (UPC)
Recercat. Dipósit de la Recerca de Catalunya
instname
ISSN: 1359-7345
1364-548X
DOI: 10.1039/c8cc09011d⟩
Popis: The very close contact between ceria–zirconia and carbon soot allows the detection of oxygen transfer from ceria–zirconia to carbon by in situ Environmental HRTEM already at low temperatures. This highlights the outstanding redox behavior and soot oxidation potential of ceria–zirconia when suitable carbon–catalyst arrangements are generated at the nanoscale.
Databáze: OpenAIRE