Push-pull amino-nitro helicenes: synthesis, (chir)optical properties and self-assembly into thin films

Autor:	Michal Šámal, Jiří Rybáček, Jan Holec, Jan Hanus, Jaroslav Vacek, Miloš Buděšínský, Lucie Bednárová, Pavel Fiedler, Michaela Šrámová Slušná, Irena G. Stará, Ivo Starý
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites Polycyclic Compounds Stereoisomerism General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications (Cambridge, England). 58(91)
ISSN:	1364-548X
Popis:	A series of regioisomeric push-pull amino-nitro [6]helicenes and a related [7]helicene derivative were prepared and their racemates resolved into enantiomers. Compared to the parent helicenes, they exhibit red-shifted UV-Vis spectra, pronounced dipole moments, altered chiroptical properties such as remarkable optical rotatory power, and can form nanocrystalline Langmuir-Blodgett films.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b901f0f3d8cb31b2182a7b0115555652 https://pubmed.ncbi.nlm.nih.gov/36314481 Zobrazit plný text záznamu