Elaboration on the Electronics of Salen Manganese Nitrides: Investigations into Alkoxy-Substituted Ligand Scaffolds
| Autor: | Gregory A. MacNeil, Tim Storr, Nicholas M. Hein |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
010405 organic chemistry
Ligand Substituent chemistry.chemical_element Manganese Nitride 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Polymer chemistry Alkoxy group visual_art.visual_art_medium Reactivity (chemistry) Physical and Theoretical Chemistry Cyclic voltammetry |
| Zdroj: | Inorganic Chemistry. 60:16895-16905 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/acs.inorgchem.1c02668 |
| Popis: | The ligand electronics of salen manganese nitride complexes directly influence the locus of oxidation and, thus, the reactivity of the resulting oxidized species. This work investigates the influence of tert-butoxy, isopropoxy, and methoxy substituents on the electronics of salen manganese nitride species and includes the first documentation of the para Hammett value for the tert-butoxy substituent (σpara = -0.13 ± 0.03). Each alkoxy-substituted complex undergoes metal-based oxidation to form manganese(VI), and the kinetics of bimolecular homocoupling to form N2 were assessed by cyclic voltammetry. Bis-oxidation of the manganese complexes was investigated at low temperature using cyclic voltammery and UV-vis-near-IR spectroscopy, and in combination with theoretical calculations, plausible electronic structures of the dications are provided. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|