Liquid marble containing degradable polyperoxides for adhesion force-changeable pressure-sensitive adhesives
| Autor: | Eriko Sato, Hideo Horibe, Takashi Nishiyama, Syuji Fujii, Yoshinobu Nakamura, Michihiro Yuri |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Materials science
易解体性接着 General Chemical Engineering polyperoxide chemistry.chemical_element リキッドマーブル 02 engineering and technology 感圧性接着(粘着) 010402 general chemistry 01 natural sciences Oxygen chemistry.chemical_compound pressure-sensitive adhesive Copolymer Organic chemistry Composite material ポリペルオキシド dismantlable adhesive General Chemistry Adhesion 021001 nanoscience & nanotechnology Decomposition 0104 chemical sciences Monomer chemistry Polymerization liquid marble Adhesive 0210 nano-technology Layer (electronics) |
| Zdroj: | RSC Advances. 6(61):56475-56481 |
| ISSN: | 2046-2069 |
| Popis: | Liquid marbles containing a sticky polyperoxide were prepared by the in situ copolymerization of the 1,3-diene monomer with oxygen. The as-prepared liquid marbles had a non-sticky nature and could move on any substrates due to the presence of hard particles on their surfaces, while the squeezed liquid marble developed adhesion force-tunable PSA properties due to the outflow of the inner materials. The 180° peel strength of the squeezed liquid marble increased by heating at 90 °C for 1 h or by UV irradiation at 0.86 J cm−2 because the cohesive force of the adhesive layer increased by the additional polymerization initiated by moderate decomposition of the polyperoxide. The increased 180° peel strengths were significantly decreased again to almost zero, i.e., dismantling, after an additional heating at 150 °C for 1 h because of an excess increase in the cohesive force as pressure-sensitive adhesives, where cross-linking took place as a result of significant decomposition of the polyperoxide accompanied by hydrogen abstraction and coupling. |
| Databáze: | OpenAIRE |
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