A novel heterocyclic atom exchange reaction with Lawesson's reagent: a one-pot synthesis of dithiomaltol
| Autor: | Daniel Brayton, Patrick J. Farmer, Seth M. Cohen, Faith E. Jacobsen |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
Models
Molecular Molecular Structure Proton Chemistry One-pot synthesis Metals and Alloys Maltol Organothiophosphorus Compounds General Medicine General Chemistry Crystallography X-Ray Medicinal chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Pyrones Reagent Atom Materials Chemistry Ceramics and Composites Organic chemistry Lawesson's reagent Dithiomaltol |
| Zdroj: | Chem. Commun.. :206-208 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/b511966a |
| Popis: | A one-pot reaction of maltol with Lawesson's reagent generates dithiomaltol, a thiopyran-4-thione, via an unusual heterocyclic atom exchange (HCAE) reaction; only pyrones with proton or aliphatic substituents undergo the HCAE substitution. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|