Construction of modular Pd/Cu multimetallic chains via ligand- and anion-controlled metal–metal interactions
| Autor: | Orestes Rivada-Wheelaghan, Robert R. Fayzullin, Ramadoss Govindarajan, Shubham Deolka, Shrinwantu Pal, Julia R. Khusnutdinova, Eugene Khaskin |
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| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Ligand Metals and Alloys Alkyne General Chemistry Bond formation Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ion Metal Crystallography chemistry visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Reactivity (chemistry) Metal metal |
| Zdroj: | Chemical Communications. 57:10206-10209 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | The presence of Pd⋯Cu and Pd⋯Pd interactions as well as the order of metal atoms in a chain held by a modular polynucleating ligand is controlled by the coordinating ability of the anions, leading to selective formation of bi- and tetranuclear Pd/Cu and Pd4 chains. Metal–metal cooperative reactivity in these complexes was tested in Ar–O bond formation and alkyne activation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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