Cascade Cyclizations of α,β-Unsaturated Thioesters: Additional Examples
Autor: | Nicholas A. Ahlemeyer, Benjamin A. Matz, David M. Leace, Matthew R Straub, Vladimir B. Birman |
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Rok vydání: | 2020 |
Předmět: | |
Zdroj: | The Journal of organic chemistry. 86(1) |
ISSN: | 1520-6904 |
Popis: | Several additional examples of cascade cyclizations of α,β-unsaturated thioesters proceeding are reported, which proceed via two distinct mechanistic pathways: enantioselective acyl transfer promoted by amidine-based catalysts (ABCs) and a racemic chain mechanism mediated by a thiolate nucleophile. |
Databáze: | OpenAIRE |
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