Qualitative colorimetric analysis of a Ir(iii )/Eu(iii ) dyad in the presence of chemical warfare agents and simulants on a paper matrix
| Autor: | Eva Micich, Alexander J. Metherell, Michael D. Ward, Andreas Zaugg, Christophe Curty, Genevieve H. Dennison |
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| Rok vydání: | 2019 |
| Předmět: |
Analyte
Chemical Warfare Agents Chemistry General Chemical Engineering Inorganic chemistry Uv absorption 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Matrix (chemical analysis) 0210 nano-technology Luminescence Colorimetric analysis |
| Zdroj: | RSC Advances. 9:7615-7619 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c9ra00824a |
| Popis: | The addition of G- and V-series organophosphorus chemical warfare agents and simulants to a paper-based assay of a dual-luminescent Ir(iii)/Eu(iii) dyad generated different emissive responses between the classes and compound types. The emission responses are complex and based not only on altering the balance between red Eu(iii)-based and blue Ir(iii)-based luminescent components, but also incorporate other factors such as analyte volatility, concentration and UV absorption. The extent of this emission colour change was analysed colorimetrically and related to the change in RGB output over time. |
| Databáze: | OpenAIRE |
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