Syntheses, Structures, and Characteristics of Three Metal Complexes Constructed Using Hexacarboxylic Acid
| Autor: | Jian Xiu, Xin Liu, Zhijun Liang, Lingshu Meng, Guanlin Guo, Lun Zhao, Xu Zhou |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
Thermogravimetric analysis
Materials science Luminescence Iron Carboxylic Acids Pharmaceutical Science Infrared spectroscopy Electrochemistry Ligands complex mixtures Isothermal process Article Analytical Chemistry Metal chemistry.chemical_compound stomatognathic system X-Ray Diffraction Coordination Complexes Drug Discovery Physical and Theoretical Chemistry Benzene chemistry.chemical_classification Ions Organic Chemistry Temperature Polymer Electrochemical Techniques respiratory system hexacarboxylic acid carbohydrates (lipids) stomatognathic diseases Crystallography Piperazine coordination polymers chemistry Chemistry (miscellaneous) visual_art fluorescent probe Thermogravimetry visual_art.visual_art_medium Molecular Medicine electrochemical behaviors |
| Zdroj: | Molecules Volume 24 Issue 24 |
| ISSN: | 1420-3049 |
| Popis: | In this study, three new 3D coordination polymers (CPs), {[Cd3(L)(H2O)6]· H2O}n (1), {[Cu1.5(L)0.5(bimb)1.5]· 5H2O· DMF}n (2), and {[Mn1.5(H3L)(bibp)0.5(H2O)2]· 3H2O}n (3) (bimb= 1,3-bis(imidazol-1-yl)benzene, bibp= 1,4-bis((4-imidazol-1-yl)benzyl)piperazine), were prepared under solvothermal or hydrothermal conditions based on a hexadentate ligand (1,3,5-triazine-2,4,6-triamine hexa-acetic acid (H6L)). Structural elucidations were carried out by IR spectra along with single-crystal X-ray diffraction analysis, while thermogravimetric analysis (TGA) (dynamic and isothermal) and XRD techniques were used for property evaluations of the polymers. Furthermore, the fluorescence properties and detection of the Fe3+ ions in 1 were tested at room temperature, and the electrochemical behavior of 2 is also stated in this article. |
| Databáze: | OpenAIRE |
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