A Biomimetic Synthesis of des-Hydroxy Paecilospirone
| Autor: | Zhen-Gao Feng, Thomas R. R. Pettus, G. Leslie Burnett |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Chemistry Diels-Alder Organic Chemistry Carbon skeleton chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences benzylic oxidation Medicinal and Biomolecular Chemistry Biomimetic synthesis ortho-quinone methide enol ether Paecilospirone Diels alder Enol ether Organic chemistry paecilospirone Carbon Lactone |
| Zdroj: | Synlett, vol 29, iss 11 SYNLETT, vol 29, iss 11 Pettus, Thomas; Feng, Zhen-Gao; & Burnett, G. (2018). A Biomimetic Synthesis of des-Hydroxy Paecilospirone. Synlett, 29(11), 1517-1519. doi: 10.1055/s-0036-1592001. UC Office of the President: Research Grants Program Office (RGPO). Retrieved from: http://www.escholarship.org/uc/item/10k7r80r |
| DOI: | 10.1055/s-0036-1592001. |
| Popis: | The carbon framework of des-hydroxy paecilospirone was rapidly synthesized using a biomimetic approach whereby an enol ether and an ortho-quinone methide (o-QM), each derived from the same lactone, were combined to arrive at the complete carbon skeleton of paecilospirone. |
| Databáze: | OpenAIRE |
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