Ceramide-epoxides

Autor: A, Möllenberg, G, Spiteller
Rok vydání: 2001
Předmět:
Zdroj: Chemistry and Physics of Lipids. 109:225-228
ISSN: 0009-3084
DOI: 10.1016/s0009-3084(00)00208-5
Popis: Previously unknown 4,5-epoxy-N-acetyl-sphingosine (1) was synthesized by epoxidation of N-acetyl-sphingosine with 1,1-dimethyldioxirane. A by-product generated by HPLC purification is the tetrahydrofuryl derivative of acetamide (2). Mainly allylic oxidation was observed when natural ceramides were reacted with dimethyldioxirane.
Databáze: OpenAIRE
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