New Cyanido-Bridged Heterometallic 3d-4f 1D Coordination Polymers: Synthesis, Crystal Structures and Magnetic Properties
| Autor: | Augustin M. Madalan, Diana Dragancea, Marius Andruh, Ghenadie Novitchi |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Lanthanide
Materials science cyanido-bridged complexes Crystal structure 010402 general chemistry 01 natural sciences Ion Magnetization chemistry.chemical_compound single molecule magnets Materials Chemistry lanthanides QD1-999 Semicarbazide 010405 organic chemistry Ligand Relaxation (NMR) Condensation reaction 0104 chemical sciences Electronic Optical and Magnetic Materials Crystallography coordination polymers Chemistry chemistry Chemistry (miscellaneous) heterometallic complexes |
| Zdroj: | Magnetochemistry Magnetochemistry; Volume 7; Issue 5; Pages: 57 Magnetochemistry, Vol 7, Iss 57, p 57 (2021) |
| ISSN: | 2312-7481 |
| DOI: | 10.3390/magnetochemistry7050057 |
| Popis: | Three new 1D cyanido-bridged 3d-4f coordination polymers, {[Gd(L)(H2O)2Fe(CN)6]·H2O}n(1GdFe), {[Dy(L)(H2O)2Fe(CN)6]·3H2O}n(2DyFe), and {[Dy(L)(H2O)2Co(CN)6]·H2O}n(3DyCo), were assembled following the building-block approach (L = pentadentatebis-semicarbazone ligand resulting from the condensation reaction between 2,6-diacetyl-pyridine and semicarbazide). The crystal structures consist of crenel-like LnIII-MIIIalternate chains, with the LnIIIions connected by the hexacyanido metalloligands through twociscyanido groups. The magnetic properties of the three complexes have been investigated. Field-induced slow relaxation of the magnetization was observed for compounds2DyFeand3DyCo. Compound3DyCois a new example of chain of Single Ion Magnets. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|