Catalytic Oxidation of Acenaphthene and Its Derivatives in Acetic Acid

Autor:	Ivan I. Kon'kov, Tatiana V. Bukharkina, Olga S. Grechishkina, Nikolai G. Digurov
Rok vydání:	2002
Předmět:	inorganic chemicals Organic Chemistry Acenaphthene chemistry.chemical_element Manganese Catalysis Quinone Acetic acid chemistry.chemical_compound chemistry Catalytic oxidation Organic chemistry Naphthalic anhydride Physical and Theoretical Chemistry Cobalt
Zdroj:	Organic Process Research & Development. 6:394-400
ISSN:	1520-586X 1083-6160
DOI:	10.1021/op0100448
Popis:	The chemistry of formation of products of acenaphthene oxidation in the presence of the catalyst containing both manganese and cobalt bromides under batch conditions is discussed. The main reaction products are acenaphthene quinone, acenaphthenol-9, trans-acenaphthylene glycol, naphthalide, and naphthalic anhydride. The sequence of reactions leading to the final products is established. It is shown that the main oxidation product in the presence of the manganese-based catalyst is naphthalic anhydride, and the main product in the presence of the cobalt-based catalyst is acenaphthene quinone. The process and engineering techniques providing for the high overall and fractional yields of the desired products are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b7bea5ca3d4ac71639ab37c3468c180d https://doi.org/10.1021/op0100448 Zobrazit plný text záznamu