Characterization of a Dinuclear (μ-Hydroxo)(μ-pyrazolato)dimanganese(II) Complex and Hydrolytic Equilibrium of the Bridging Pyrazolate Ligand

Autor:	Shiro Hikichi, Munetaka Akita, Shinobu Ichikawa, Yoshihiko Moro-oka, Hidehito Komatsuzaki
Rok vydání:	1998
Předmět:	Inorganic Chemistry chemistry.chemical_compound Hydrolysis chemistry Stereochemistry Physical and Theoretical Chemistry Pyrazole ligands Pyrazole Medicinal chemistry
Zdroj:	Inorganic Chemistry. 37:3652-3656
ISSN:	1520-510X 0020-1669
Popis:	Reaction of the dinuclear bis(μ-hydroxo) complex 2 with 3,5-diisopropylpyrazole yielded a dinuclear (μ-hydroxo)(μ-pyrazolato)dimanganese(II) complex 4, which reacted with H2O2 in the absence of excess pyrazole to give the mononuclear Mn(III) side-on peroxo complex containing a neutral pyrazole ligand. However, hydrolytic equilibrium of the bridging pyrazolate ligand of the (μ-hydroxo)(μ-pyrazolato)dimanganese(II) complex was observed in the presence of H2O.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b7be3052eba934b93cbee99963950be1 https://doi.org/10.1021/ic971622x Zobrazit plný text záznamu