Synthesis, characterization and experimental, theoretical, electrochemical, antioxidant and antibacterial study of a new schiff base and its complexes
| Autor: | Sadin Özdemir, Abdussamet Oztomsuk, Salih Ilhan, Mauricio Cornejo, Veysi Okumuş, Haci Baykara, Abdulkadir Levent, M. Salih Seyitoglu |
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| Přispěvatelé: | Fen - Edebiyat Fakültesi, Okumuş, Veysi, Batman Üniversitesi Fen - Edebiyat Fakültesi Kimya Bölümü |
| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: |
Magnetic Resonance Spectroscopy
Cyclic voltammetry Inorganic chemistry Molecular Conformation Normal Distribution Molar conductivity Ligands Antioxidants Mass Spectrometry Analytical Chemistry Electrolytes Magnetics chemistry.chemical_compound 1 6-Bis(4-chloro-2-aminophenoxy)hexane Anti-Infective Agents Picrates Spectroscopy Fourier Transform Infrared Electrochemistry Hexanes Instrumentation Schiff Bases Spectroscopy Salicyaldehyde Chelating Agents Aniline Compounds Schiff base Mass Spectra Gaussian 09 and HOMO–LUMO Chemistry Ligand Phenyl Ethers Biphenyl Compounds Biological activities Tetrahedral molecular geometry Mass Spectra Free Radical Scavengers Atomic and Molecular Physics and Optics Anti-Bacterial Agents Biphenyl compound Crystallography Salicylaldehyde Octahedron Metals Gaussian 09 and HOMO–LUMO Thermogravimetry Spectrophotometry Ultraviolet 1 6-Bis (4-chloro-2-aminophenoxy) Hexane |
| Popis: | A new Schiff base ligand was synthesized by reaction of salicylaldehyde with 1,6-bis(4-chloro-2-aminophenoxy) hexane. Then the Schiff base complexes were synthesized by metal salts and the Schiff base. The metal to ligand ratio of metal complexes was found to be 1:1. The Cu(II) complex is proposed to be square planar and the Co(II), Ni(II), Mn(II) and Zn(II) complexes are proposed to be tetrahedral geometry. The Ti(III) and V(III) complexes are proposed to be a capped octahedron in which a seventh ligand has been added to triangular face. The complexes are non-electrolytes as shown by their molar conductivities (KM). The structure of metal complexes is proposed from elemental analysis, FT-IR, UV–vis, magnetic susceptibility measurements, molar conductivity measurements, Mass Spectra and thermal gravimetric analysis. In addition antimicrobial and antioxidant studies, cyclic voltammetry of the complexes, theoretical 1H NMR and HOMO–LUMO energy calculations of the new di-functional ligand were done. |
| Databáze: | OpenAIRE |
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