Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes
| Autor: | Hubert Theil, Hartmut Bögge, Thorsten Glaser, Anja Stammler, Bastian Feldscher |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
Magnetic Resonance Spectroscopy
Molecular Structure Ligand chemistry.chemical_element Nuclear magnetic resonance spectroscopy Photochemistry Crystallography X-Ray Ligands Copper Hydroquinones Inorganic Chemistry Crystallography chemistry Superexchange Benzene derivatives Spectroscopy Fourier Transform Infrared Benzene Derivatives Organometallic Compounds Molecule Sulfhydryl Compounds Physical and Theoretical Chemistry Group 2 organometallic chemistry |
| Popis: | An unprecedented trinucleating ligand with a central 1,3,5-trimercaptobenzene unit and its trinuclear Cu(II)(3) complex are presented. The high covalency of the difficult-to-realize Cu(II)-SR bond provides an order of magnitude increase in the superexchange interaction in comparison to its oxygen analogue. |
| Databáze: | OpenAIRE |
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