Electrophilic Nitration of meso-Tetraarylporphyrin Complexes at the β-Pyrrolic Position

Autor:	Stanislaw Ostrowski, Dorota Szerszen, Marek Ryszczuk
Rok vydání:	2005
Předmět:	Inorganic chemistry Organic Chemistry chemistry.chemical_element General Medicine Copper Medicinal chemistry Catalysis Nickel chemistry.chemical_compound chemistry Nitration Polymer chemistry Electrophile Cobalt
Zdroj:	Synthesis. 2005:819-823
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-2005-861853
Popis:	The selective nitration of meso-tetraphenylporphyrin complexes is described. The reaction of the above porphyrinates with 25% HNO 3 or 5% HNO 3 at room temperature or 0-5 °C, respectively, results in the formation of the corresponding mono β-nitroporphyrins (56-81%), accompanied by small amounts of a mixture of β,β-dinitro by-products. The results described above are the first known examples of β-mononitration of meso-tetraarylporphyrin complexes under electrophilic conditions. Reactions with nickel(II), copper(II), and cobalt(II) porphyrinates are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b7344303f9f31c4eaaeaa18cf56e1b0d https://doi.org/10.1055/s-2005-861853 Zobrazit plný text záznamu