Photofluorination of Aliphatic C-H Bonds Promoted by the Phthalimide Group
| Autor: | Yoshitaka Hamashima, Yuji Kawato, Shuya Masuda, Hiromichi Egami |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Regioselectivity 010402 general chemistry 01 natural sciences Biochemistry Medicinal chemistry 0104 chemical sciences Catalysis Phthalimide chemistry.chemical_compound chemistry Group (periodic table) Physical and Theoretical Chemistry Bond energy Selectfluor Reaction site |
| Zdroj: | Organic letters. 20(5) |
| ISSN: | 1523-7052 |
| Popis: | Aliphatic C–H fluorination of phthalimide derivatives with Selectfluor was investigated under photoirradiation conditions. The reaction did not require any additive or catalyst and afforded C–H fluorinated products in moderate to good yields. It is likely that the reaction site depends on the C–H bond energy, and this may be the reason for the good to high regioselectivity. |
| Databáze: | OpenAIRE |
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