Application of GaCp as a Ligand in Coordination Chemistry: Similarities and Differences to GaCp*

Autor:	Briac Tobey, Andreas Schnepf, Dominik Naglav
Rok vydání:	2013
Předmět:	Inorganic Chemistry chemistry.chemical_classification chemistry.chemical_compound chemistry Cyclooctene Reducing agent Ligand Chemie Organic chemistry chemistry.chemical_element Gallium Medicinal chemistry Coordination complex
Zdroj:	European Journal of Inorganic Chemistry. 2013:4146-4149
ISSN:	1099-0682 1434-1948
DOI:	10.1002/ejic.201300401
Popis:	Solid “GaI” reacts with NaCp to give (η5-cyclopentadienyl)gallium (GaCp). Further reaction of a solution of GaCp with [Cr(CO)5(coe)] (coe = cyclooctene) or Co2(CO)8 leads to CpGa–Cr(CO)5 (1) or (thf)GaCp{Co(CO)4}2 (4), respectively, which shows that GaCp can be used as a terminal ligand in coordination chemistry, but unlike its bulkier analogue GaCp* (Cp* = C5Me5), it also acts as a reducing agent.
Databáze:	OpenAIRE
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