The effect of nanostructures on high pressure intrusion–extrusion of water and electrolyte solutions in hierarchical nanoboxes of silicalite-1
| Autor: | Joffrey Huve, Andrey Ryzhikov, T. Jean Daou, Joël Patarin, Habiba Nouali |
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| Přispěvatelé: | Institut de Science des Matériaux de Mulhouse (IS2M), Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Matériaux et Nanosciences Grand-Est (MNGE), Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS), Ryzhikov, Andrey, Centre National de la Recherche Scientifique (CNRS)-Matériaux et nanosciences d'Alsace (FMNGE), Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA) |
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
Nanostructure
02 engineering and technology Electrolyte 010402 general chemistry 01 natural sciences Catalysis chemistry.chemical_compound [CHIM] Chemical Sciences Materials Chemistry [CHIM]Chemical Sciences ComputingMilieux_MISCELLANEOUS [CHIM.MATE] Chemical Sciences/Material chemistry Aqueous solution Chemistry General Chemistry [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry Silanol [CHIM.THEO] Chemical Sciences/Theoretical and/or physical chemistry Volume (thermodynamics) Nanocrystal Chemical engineering Extrusion 0210 nano-technology Mesoporous material |
| Zdroj: | New Journal of Chemistry New Journal of Chemistry, In press, ⟨10.1039/C9NJ01891C⟩ New Journal of Chemistry, Royal Society of Chemistry, In press, ⟨10.1039/C9NJ01891C⟩ |
| ISSN: | 1144-0546 1369-9261 |
| Popis: | This study of high pressure intrusion–extrusion of water and 20 M LiCl solution in silicalite-1 nanoboxes demonstrates how nanostructures can determine the properties of materials. The drastic effect of the presence of cavities on the intrusion–extrusion behavior and characteristics has been observed, particularly, in the case of LiCl aqueous solution. The nanoboxes demonstrate a combination of bumper and spring behavior in the first intrusion–extrusion cycle. The intrusion of 20 M LiCl solution is only partially reversible and takes place in two clearly marked steps, whereas only one intrusion step with a fully reversible spring behavior is observed for the micro- and nanocrystals. The first step, with an intruded volume of 0.07 mL g−1 and an intruded pressure of 98 MPa, is irreversible and corresponds probably to the filling of mesoporous cavities, and the second one, with an intruded volume of 0.08 mL g−1 and an intrusion pressure of 273 MPa, is fully reversible and related to the filling of the micropores of silicalite-1 walls. The filling of the nanocavities occurs probably through small mesoporous cracks in the nanobox walls. The characterization by structural and physicochemical methods shows that the dissolution–recrystallization process leads to the formation of a MFI structure with lower content of silanol defects in comparison with initial nanocrystals explaining the steeper slope of the intrusion step and the higher intrusion pressure observed for the “nanobox–H2O” and “nanobox–20 M LiCl” systems. |
| Databáze: | OpenAIRE |
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