Isolation and Characterization of Carbene Derivatives of La@C82(Cs)

Autor:	Michael T. H. Liu, Takayoshi Kono, Takahiro Tsuchiya, Takatsugu Wakahara, Shigeru Nagase, Naomi Mizorogi, Takeshi Akasaka, Tatsuhisa Kato, Yutaka Maeda, Zdenek Slanina, Yoichiro Matsunaga, Tsukasa Nakahodo, Midori O. Ishitsuka
Rok vydání:	2008
Předmět:	chemistry.chemical_compound chemistry law Stereochemistry Physical and Theoretical Chemistry Electron paramagnetic resonance Selectivity High-performance liquid chromatography Carbene Electronic properties law.invention Adduct
Zdroj:	The Journal of Physical Chemistry A. 112:1294-1297
ISSN:	1520-5215 1089-5639
DOI:	10.1021/jp7097747
Popis:	The photochemical reaction of La@C82(Cs) with 2-adamantane-2,3-[3H]-diazirine (1) affords the adduct 2 of La@C82(Cs) with adamantylidene (Ad:) in a high selectivity. The two isomers of La@C82(Cs)(Ad), 2a and 2b, are isolated by HPLC and characterized by electron spin resonance, mass, and UV-vis-near-infrared spectroscopies. The electronic properties of 2a and 2b are very similar to that of the pristine La@C82(Cs), suggesting that 2a and 2b retain the essential electronic and structural character of La@C82(Cs).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b67ba573ed09da1c46eebdc8874fb88b https://doi.org/10.1021/jp7097747 Zobrazit plný text záznamu