A Multifunctional Dual-Luminescent Polyoxometalate@Metal-Organic Framework EuW10@UiO-67 Composite as Chemical Probe and Temperature Sensor
| Autor: | Catherine Roch-Marchal, Pierre Mialane, Grégoire Paille, William Salomon, Anne Dolbecq, Hélène Serier-Brault, Rémi Dessapt |
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| Přispěvatelé: | Institut Lavoisier de Versailles (ILV), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Chimie des Processus Biologiques (LCPB), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut des Matériaux Jean Rouxel (IMN), Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Ecole Polytechnique de l'Université de Nantes (EPUN), Université de Nantes (UN)-Université de Nantes (UN), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS), Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Ratiometric Luminescent Thermometer Composite number chemistry.chemical_element 02 engineering and technology [CHIM.INOR]Chemical Sciences/Inorganic chemistry 010402 general chemistry 01 natural sciences Metal-Organic Framework lcsh:Chemistry Europium [CHIM]Chemical Sciences [CHIM.COOR]Chemical Sciences/Coordination chemistry ComputingMilieux_MISCELLANEOUS Sensor Zirconium Polyoxometalate General Chemistry [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences chemistry Chemical engineering lcsh:QD1-999 Elemental analysis Metal-organic framework Crystallite 0210 nano-technology Luminescence |
| Zdroj: | Frontiers in Chemistry Frontiers in Chemistry, Frontiers Media, 2018, 6, ⟨10.3389/fchem.2018.00425⟩ Frontiers in Chemistry, Vol 6 (2018) Frontiers in Chemistry, Frontiers, 2018, 6, ⟨10.3389/fchem.2018.00425⟩ |
| ISSN: | 2296-2646 |
| Popis: | International audience; The luminescent [EuW10O36]9− polyoxometalate has been introduced into the cavities of the highly porous zirconium luminescent metal-organic framework UiO-67 via a direct synthesis approach, affording the EuW10@UiO-67 hybrid. Using a combination of techniques (TGA, BET, elemental analysis, EDX mapping,…) this new material has been fully characterized, evidencing that it contains only 0.25% in europium and thatthe polyoxometalate units are located inside the octahedral cavities and not at the surface of the UiO-67 crystallites. Despite the low amount of europium, it is shown that EuW10@UiO-67 acts as a solid-state luminescent sensor for the detection of amino-acids, the growth of the emission intensity globally following the growth of the amino-acid pKa. In addition, EuW10@UiO-67 acts as a sensor for the detection ofmetalliccations, with a high sensitivity for Fe3+. Noticeably, the recyclability of the reported material has been established. Finally, it is shown that the dual-luminescent EuW10@UiO-67 material behave as a self-calibrated-ratiometric thermometer in the physiological range. |
| Databáze: | OpenAIRE |
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