Visible-Light-Initiated Multicomponent Reactions of α-Diazoesters to Access Organophosphorus Compounds
| Autor: | Chengming Qu, Jindong Hao, Hongyu Ding, Yufen lv, Xian-En Zhao, Xiaohui Zhao, Wei Wei |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | The Journal of Organic Chemistry. 87:12921-12931 |
| ISSN: | 1520-6904 0022-3263 |
| Popis: | A simple visible-light-initiated strategy has been established for the construction of organophosphorus compounds via aerobic multicomponent reaction of α-diazoesters, cyclic ethers, and P(O)H compounds under air. A number of phosphonates and phosphinates could be efficiently isolated in moderate to good yields without the use of photosensitizers and metal reagents. This multicomponent reaction has advantages of mild condition, simple operation, eco-friendly energy, good functional-group tolerance, and gram-scale synthesis. |
| Databáze: | OpenAIRE |
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